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         Molecular Geometry of molecule is the three-dimensional arrangement of atoms in a molecule. It follows the Valence Shell Electron Pair Repulsion (VSEPR) theory which assumes that each atom in a molecule will be positioned so that there is minimal repulsion between the valence electron of that atom.

 

 

 

 

 

 

 

 

 

 

 

 

 

Wherein,

 

 

 

 

 

 

 

  • Bent/V-shaped/ Angular (AX2E1)

              - two bonding pairs and one nonbonding pair.

                          SO­2                                   6 + (2) 6=18 e - 4=14 e-

 

 

 

 

 

 

 

 

 

 

 

  • Trigonal Pyramidal (AX3E1)

                -three bonding pairs and one nonbonding pair.

 

 

 

 

 

 

 

 

 

 

  • Bent/ V-shaped/ Angular (AX2E2).  120 degrees

                  -two bonding pairs and two nonbonding pairs

 

 

 

 

 

 

 

 

  • Distorted Tetrahedron/ See-saw (AX4E1)

          -four electron domains are bonding pairs and one nonbonding pair

                      SF4                             6 + 7 (4)=34 e – 8=26 e-

 

 

 

 

 

 

 

 

 

 

  • T- shaped (AX3E2)

          -Three electron domains are bonding pairs and two are nonbonding pairs.

 

 

 

 

 

 

 

 

 

 

  • Linear (AX2E3)

          - two electron domains are bonding pairs and three are nonbonding pairs

 

 

 

 

 

 

 

 

  • Square Pyramidal (AX5E1)

                     - five electrons domains are bonding pairs with one lone pair

                    BrF5                                  7 + (5) 7=42 e – 10=32e-

 

 

 

 

 

 

 

 

 

 

  • Square Planar (AX4E1)

              -four electrons domains are bonding pairs with two lone pairs.

 

 

PROCESS OF MOLECULAR GEOMETRY

With the Help of Lone Pairs

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